化学考试大纲及试卷组成

sunwei0UID：2227404

I. ANALYTICAL CHEMISTRY — 15%

• Data Acquisition and Use of Statistics — Errors, statistical considerations
• Solutions and Standardization — Concentration terms, and primary standards
• Homogeneous Equilibria — Acid-base, oxidation-reduction, complexometry
• Heterogeneous Equilibria — Gravimetric analysis, solubility, precipitation titrations, chemical separations
• Instrumental Methods — Electrochemical methods, spectroscopic methods, chromatographic methods, thermal methods, calibration of instruments
• Environmental Applications
• Radiochemical Methods — Detectors, applications

II. INORGANIC CHEMISTRY — 25%

• General Chemistry — Periodic trends, oxidation states, nuclear chemistry
• Ionic Substances — Lattice geometries, lattice energies, ionic radii and radius/ratio effects
• Covalent Molecular Substances — Lewis diagrams, molecular point groups, VSEPR concept, valence bond description and hybridization, molecular orbital description, bond energies, covalent and van der Waals radii of the elements, intermolecular forces
• Metals and Semiconductors — Structure, band theory, physical and chemical consequences of band theory
• Concepts of Acids and Bases — Brønsted-Lowry approaches, Lewis theory, solvent system approaches
• Chemistry of the Main Group Elements — Electronic structures, occurrences and recovery, physical and chemical properties of the elements and their compounds
• Chemistry of the Transition Elements — Electronic structures, occurrences and recovery, physical and chemical properties of the elements and their compounds, coordination chemistry
• Special Topics — Organometallic chemistry, catalysis, bioinorganic chemistry, applied solid-state chemistry, environmental chemistry

III. ORGANIC CHEMISTRY — 30%

• Structure, Bonding, and Nomenclature — Lewis structures, orbital hybridization, configuration and stereochemical notation, conformational analysis, systematic IUPAC nomenclature, spectroscopy (IR and 1H and 13C NMR)
• Functional Groups — Preparation, reactions, and interconversions of alkanes, alkenes, alkynes, dienes, alkyl halides, alcohols, ethers, epoxides, sulfides, thiols, aromatic compounds, aldehydes, ketones, carboxylic acids and their derivatives, amines
• Reaction Mechanisms — Nucleophilic displacements and addition, nucleophilic aromatic substitution, electrophilic additions, electrophilic aromatic substitutions, eliminations, Diels-Alder and other cycloadditions
• Reactive Intermediates — Chemistry and nature of carbocations, carbanions, free radicals, carbenes, benzynes, enols
• Organometallics — Preparation and reactions of Grignard and organolithium reagents, lithium organocuprates, and other modern main group and transition metal reagents and catalysts
• Special Topics — Resonance, molecular orbital theory, catalysis, acid-base theory, carbon acidity, aromaticity, antiaromaticity, macromolecules, lipids, amino acids, peptides, carbohydrates, nucleic acids, terpenes, asymmetric synthesis, orbital symmetry, polymers

IV. PHYSICAL CHEMISTRY — 30%

• Thermodynamics — First, second, and third laws, thermochemistry, ideal and real gases and solutions, Gibbs and Helmholtz energy, chemical potential, chemical equilibria, phase equilibria, colligative properties, statistical thermodynamics
• Quantum Chemistry and Applications to Spectroscopy — Classical experiments, principles of quantum mechanics, atomic and molecular structure, molecular spectroscopy
• Dynamics — Experimental and theoretical chemical kinetics, solution and liquid dynamics, photochemistry

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愚沐山人UID：3223422

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