1 过渡态理论中那个k的长长的公式
Both the Arrhenius and the Eyring equation describe the temperature dependence of reaction rate. Strictly speaking, the Arrhenius equation can be applied only to gas reactions. The Eyring equation is used in the study of gas, condensed and mixed phase reactions - all places where the simple collision model is not very helpful. The Arrhenius equation is founded on the empirical observation that conducting a reaction at a higher temperature increases the reaction rate. The Eyring equaion is a theoretical construct, based on transition state model.