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发表于 2010-4-23 23:58:06
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Background reading
Biodiesel[生物柴油]
Oil in your coffee
Feb 4th 2009
From Economist.com
A new source of fuel production
RUNNING a diesel engine on a plant-based fuel is hardly a new idea. Indeed, one of the early demonstrations shown by [Rudolph Diesel], the German engineer who invented the engines at the end of the 1800s, operated on pure peanut oil. Diesel fuel made from crude oil eventually [won the day] because it was easier to use and cheaper to produce. Now new forms of biodiesel are starting to change the picture again. And one of the latest sources comes from the remains of a drink enjoyed the world over: coffee.
Biodiesels are becoming increasingly popular. In America, Minnesota has [decreed颁布命令] that all diesel sold in the state has to contain 2% biodiesel (much of it from the crops grown by the state’s soya farmers). Biodiesel can also be found blended into the fuel used by public and commercial vehicles and by trains in a number of countries. Aircraft-engine makers are also testing biofuel blends. Because biodiesels can be made from materials derived from plants, which use carbon dioxide to grow, they potentially have a much lower [carbon footprint碳排放量] than petroleum-based fuels.
Coffee is also a plant product, but once the beans are ground[压迫研磨] and used they end up being thrown away or put on gardens as compost[堆肥混合肥]. Narasimharao Kondamudi, Susanta Mohapatra and Manoranjan Misra of the University of Nevada at Reno have found that coffee grounds can yield by weight 10-15% of biodiesel relatively easily. Moreover, when run in an engine the fuel does not have an offensive smell—just [a whiff of] coffee. Some biodiesels made from used cooking-oil leave a car exhaust smelling like a fast-food joint. And after the diesel has been extracted, the coffee grounds can still be used for compost.
The researchers’ work began two years ago when Dr Misra, a heavy coffee drinker, left a cup unfinished and the next day noticed that the coffee was covered by [a film of] oil. Since he was investigating biofuels, Dr Misra [enlisted赢得支持] his colleagues to look at coffee’s potential. The nearby Starbucks was happy to oblige[赐] by supplying grounds.
They found that coffee biodiesel [is comparable to比得上] the best biodiesels on the market. But unlike soya and other plant-based biodiesels, it does not use up plants or land that might otherwise be planted with food crops.
Unmodified[未改变的] oils from plants, like the peanut oil used by Diesel, have a high viscosity[粘度] and require engine alterations[改变]. Diesel fuel is less thick and usually can be burned in an engine with little or no tinkering[焊补,修补]. The diesel-extraction for coffee grounds is similar to that used for other vegetable oils. It [employs a process] called transesterification[酯基转移], which reacts the grounds with an alcohol in the presence of a catalyst.
The researchers start off by drying their coffee grounds overnight and then pour in some common chemical solvents[溶剂], such as hexane[乙烷], ether[乙醚] and dichloromethane, to dissolve the oils. The grounds are then [filtered out过滤掉] and the solvents separated (to be reused with the next batch of coffee grounds). The remaining oil is treated with an alkali碱 to remove free fatty acids 游离脂肪酸(which form a soap). Then transesterification takes place by heating the crude biodiesel to about 100 degrees Celsius to remove any water, and treating it with methanol甲醇 and a catalyst. On cooling to room temperature and left to stand, the biodiesel floats up, leaving a layer of glycerine at the bottom. These layers are separated and the remaining biodiesel cleaned to remove any residues.
Although some people try to brew[酿造] their own diesel at home from leftovers[遗留物] and recycled cooking oils, coffee-based diesel seems better suited to larger-scale processes. Dr Misra says that 1 litre of biodiesel requires 5-7 kg of coffee grounds, depending on the oil content of the coffee used. In their laboratory his team has set up a one-gallon-a-day production facility, which uses between 19-26kg of coffee grounds. The biofuel should cost about $1 per gallon to make in a medium-sized installation[中等大小体格], the researchers estimate.
Commercial production might be suitable for an operation that collects coffee grounds from big coffee chains and cafeterias. There is plenty available: a report by the United States Department of Agriculture says that annual world coffee demand consumes more than 7m tonnes of coffee, which the researchers estimate could produce some 340m gallons of biodiesel. [Time, perhaps, for another cup before refilling the car.形象地说还得有段时间]
About this debate
The petrol-powered engine's life is drawing noisily towards its close[在使命将终结时,又开始讨论]. But what will replace it? One possibility is just to replace the petrol. Biofuels burn just as well and don't contribute to global warming. Or do they? Land needs to be cleared to grow them, and making them needs energy. Electric cars have better acceleration and really are zero emission. Or are they? Not if the electricity is made by burning coal.
Opening statements
Defending the motion
Alan Shaw Ph.D.
President & Chief Executive Officer, Codexis
Cars of the future may be more like the cars of today than some think. It is the fuel that will be different.
Against the motion
Sidney Goodman
Vice President, Automotive Alliances
When Great Britain entered the first world war, its First Lord of the Admiralty was concerned about his fleet.
The moderator's opening remarks[仲裁观点]
May 22nd 2009 | Mr Geoff Carr
Though the price of oil has fallen from the dizzy[让人头晕的,昏厥的] heights of last summer, the stuff is still expensive by historical standards, and [the palest of green shoots of recovery have been enough to cause an uptick最苍白无力的回复(绿芽)又开始上扬了]. Oil is getting scarcer. It is concentrated in parts of the world not [noted for以…著名] their political stability. And burning it is a huge source of man-made carbon dioxide, with all its [attendant伴随的] risk of climate change. One way or another, then, the age of oil is drawing towards its close. The question is, what will replace it as the source of power for motive power.
Several contenders have been tried and [found wanting被发现不合格]. In particular, hydrogen, either burned directly in internal combustion engines or used to make electricity in fuel cells, has been [touted被吹捧] around for decades. The so-called hydrogen economy has, though, failed to materialise. The gas is explosive and hard to handle. It is also hard to store in a form dense enough to be a plausible[合理的 on-board] fuel. Its boiling point is only 20 degrees above absolute zero, so carrying it liquid in tanks is tricky[棘手的]. And attempts to absorb it in large quantities into special reservoirs made of things such as carbon nanotubes[纳米碳管] have proved equally futile as a practical technology. Hydrogen cars, then, are going nowhere.
Instead, and surprisingly rapidly, two ideas from the dawn of motoring have been revived. Before the dominance of petrol and its cousin diesel, there were serious attempts to make battery-powered electric cars and also cars powered by ethanol. These two approaches were driven off the road as more and more oil was found and [an oil-based infrastructure achieved economies of scale基础设施获得了规模经济效应]. Now, however, with better technology, both are back. Cars powered by batteries and by biofuels, such as ethanol, are [making headway有进展] in the marketplace. But the two use very different technological approaches and, in the long run, it is doubtful whether there is room for both. We are therefore delighted to have two of the leaders of the rival approaches to debate the merits of each cause.
Proposing[defend辩护,提议] the motion is Alan Shaw, the boss of Codexis. His firm uses techniques that mimic sexual reproduction and natural selection to create artificial enzymes that perform tasks no natural enzyme can manage. Among these is the synthesis of chemicals that can be used as motor fuels. These chemicals, such as octanol, a heavier relative of the ethanol used as biofuel today, make good substitutes for petrol, and can also be mixed with it. Codexis is already dealing with Royal Dutch Shell, one of the world's largest oil companies, to commercialise this approach.
Opposing the motion we have Sidney Goodman. Mr Goodman is vice-president of automotive alliances at Better Place, an electric-car company that is building the infrastructure needed to support such vehicles in Israel, and plans to do the same in Denmark and Hawaii. His firm, too, relies on a fairly new technology: large-sized versions of the lithium-ion batteries now used to power laptop computers and mobile phones. Better Place's vehicles can be recharged in the normal way, by plugging them into the [electricity grid电力电网], but their [battery packs电池组] can also be replaced in a matter of minutes at special roadside filling stations.
Both approaches have their virtues and vices[善恶得失]. The biggest virtue of biofuels from the consumer's point of view is continuity. Next-generation biofuels of the sort Dr Shaw is developing will burn in existing engines without those engines having to be modified. The production lines in Nagoya, Wolfsburg and (assuming it gets past its current difficulties) Detroit, will not have to be retooled[重新装备], nor will car-owners have to learn new habits.
The consumer virtue of electric cars, paradoxically, is the opposite. Because they are a new, disruptive technology, they provide an opportunity for a complete redesign. Most of those now on the drawing-board will look familiar, but already engineers are starting to play, as the three-wheeled Aptera, which will be available later this year, demonstrates. Also, electric cars have high acceleration and no need for a [gear box齿轮箱]. It is surely no coincidence that one of the first on the market, the Tesla, is a top-of-the-range sports car.
Environmentally, both technologies are green, but not necessarily as green as they might appear at first sight. Being made from plants (which draw their carbon from the air), biofuels make no net contribution of carbon dioxide to the atmosphere. That is good. But plants have to be grown, and that takes land, some of which may previously have been virgin forest, which is bad. Batteries produce no carbon dioxide at all, of course. But they have to be recharged using electricity which comes from power stations. If that means burning more coal rather than, say, building more wind turbines, then that is bad, too.
Which of these technologies will dominate the future, then, is truly moot[未决的]. At the moment, they look evenly balanced[同样平衡的], but both are changing rapidly. Which [makes the greater strides更大迈步] towards cheapness and efficiency will obviously have an effect on the outcome, as will external factors such as how quickly electricity grids can be upgraded to [cope with应付] the extra demand that a widespread adoption of electric cars would require (biofuels need no such change in the infrastructure) and whether political will gathers behind one or the other.
All these areas, and others I have no doubt missed, will be explored by Dr Shaw and Mr Goodman over the coming days. As both a neutral observer and an interested party, I, for one, am looking forward to it [immensely极度地,无限地期待].
The proposer's opening remarks
May 22nd 2009 | Alan Shaw Ph.D.
Cars of the future may be more like the cars of today than some think. It is the fuel that will be different. This fuel will come from sustainable sources. It will be produced closer to where it is used. It will be cleaner. In short, it will be advanced biofuel.
第一个论点,出于环境的考虑This is important to all of us concerned about the environment. Why? In reality, most cars of the future will be powered like the cars of today. Generations of automobiles, including today's models and most to come, rely on the internal combustion engine. Meanwhile, replacement of existing cars will not be instantaneous[立即,以后再也不用immediately了!!]. According to AAA (American Automobile Association), there are over 240m vehicles in the United States. Passenger cars had a median age of about nine years in 2006, and this median age has been steadily rising since 2001. Cars and trucks 11 years and older now account for more than a third—36%—of vehicles on the road. As the recession continues to affect new car purchases, these ages are likely to rise. [举例说明现在的车没有太多改变,以后会淘汰]
As cars are replaced, future cars that consumers will buy must be affordable and convenient to operate. Gasoline (petrol) and diesel are the most affordable and convenient fuels of the last century, and they remain so today. However, in recent years the sustainability of petroleum-derived gasoline and diesel has been questioned. What will future fuels be like? Future fuels must [be compatible with以后别用suitable了] existing car engines and the current fuel delivery infrastructure. And all of us as global citizens will demand that fuel be cleaner and sustainable. The biofuels of the future will meet those tests. They will be made from biomass, engineered by modern biotechnology to be renewable and clean and practical for customers to find and use, right down to the corner filling station.
Next generation biofuels offer [compelling advantages压倒性优势]. First, they perform much like gasoline and diesel today. In industry [parlance用语], these are called "fungible"可替代的, meaning they are interchangeable within the existing fuel supply. They will also be compatible with existing vehicles and fuel distribution systems, [bypassing绕过] the need for costly new delivery infrastructure systems. Use of advanced biofuels will also eliminate concern about a "blend wall", since they can be blended in any concentration with petrochemical fuels, increasing their penetration.
In the future, car owners will not need to change how they buy or use fuel. [A good analogy类比论证] from our home here in Silicon Valley is Web 2.0 software, where changes to online applications are immediately available to every user. No need to buy new hardware, wait for upgrades or hope it works when installed.
Biofuels will be the most sustainable and [environmentally compatible和环境兼容] transportation fuels. First-generation transportation biofuels, such as corn-based ethanol, have been useful in reducing dependence on fossil fuels. However, they have not been efficient enough in energy output, and complex issues concerning food prices and land use have been raised. In the future, [commercially viable商业上可行], fungible biofuels will be based on multiple[多种的] non-food feedstocks[原料], sourced locally near fuel production sites.
Today, significant public and private resources are being poured into making our cars more efficient. We expect continued technology advances, towards our common goal of protecting the environment. Electric-battery vehicles, for example, are based on important new technology which we believe will have a role in the future. However, significant near-term challenges remain.
Performance issues such as suboptimal battery life and storage capacity are well known[性能问题,比如最优的电池寿命、储存能力]. But the potential impact on the environment is, ironically, one of the main issues concerning electric vehicles[电动车]. First, electric-battery vehicles would be charged—predominantly主要的—on coal-produced power, which [is well documented as=well proved/justified as] a significant source of greenhouse gases that contribute to global warming. Clearly, generating more coal-based power to charge electric cars would also generate additional pollution.
Second, battery-powered cars will likely depend on lithium, a raw material already in high demand from the computer industry. This raises concerns about potential environmental harm in the less-developed countries where lithium is found. In addition, the environmental impact of [expended battery disposal耗尽的电池处理] will need to be addressed. These obstacles may create challenges to the widespread availability and adoption of practical, affordable electric vehicles.
Another barrier to plug-in rechargeable, battery-driven cars is the reliance on our weak, antiquated[陈旧的] power transmission infrastructure. In the United States alone, [a report from the Electric Power Research Institute estimates报告引用形式!] that the country currently has enough extra electric capacity to charge 1m cars overnight. But there are more than 240 m vehicles now in use. An estimated 30m or more electric cars added to the transportation fleet in the next decade could severely tax an already strained system.
The current US power grid is [woefully inadequate=disappointedly insufficient] and in need of significant upgrades. Experts say the US system is not capable of reliably and safely meeting the energy challenges facing us now and in coming decades. Further, the areas of greatest wind and solar potential may not be close enough to the grid system, triggering siting and other debates that could fracture otherwise sound alliances.[触发了选址等讨论,这些讨论引起了分歧而不是坚实的联盟] Consider, for example,[ environmentalists] who are split between upholding the Endangered Species Act when debating the fate of the desert tortoise over siting solar panels and transmission infrastructure in the Mojave Desert on the grid, for broader distribution[这只是一个成分。。].
We expect vigorous debate to continue among scientists and others about the future of transportation fuel. This is healthy and ensures that all viewpoints are heard. In the end, we all agree transportation pollution must be reduced.[ For this goal to be met], the fuel of the future must be accessible and affordable for consumers, as well as cleaner. Otherwise, it will make no difference, because it will remain a laboratory curiosity or [niche marketing opportunity缝隙市场的机会]. Next-generation biofuels, derived from renewable natural sources, are a practical step in the right direction.
The opposition's opening remarks
May 22nd 2009 | Sidney Goodman
When Great Britain entered the first world war, its [First Lord of the Admiralty英国海军大臣] was concerned about his fleet[舰队]. All the ships were powered in the same way—by burning coal—and the young Winston Churchill observed that the interests of security required a diversification of the fuel mix so that no nation was dependent on a single means of fuel or energy. And so he introduced into the fleet refined petroleum, which [set off a series of events引起了连锁反应] that, ironically enough, led nearly the entire transportation world to come to depend on that same fuel. Today, roughly 98% of the world's surface transportation is powered by refined crude oil. Ask people about what that mix will look like a generation from now, and you [are bound to一定要] hear the same solution that motivated Churchill-diversity, so that again, no nation or economy is completely reliant on an single means of fuel.
先从对立面说起,讲到对立面的难处,然后引致所要表达的观点[Diversity] in fuel sources is not an undesirable objective. However, it is often confused with something else: [delivery]. Future transportation can diversify its mix of molecules—can substitute refined crude for harvested produce like corn or sugarcane—or other feed stocks still being developed in the lab. But as we look beyond the world of transportation we rarely see molecules used as a driver. And there is a very good reason for that. Electrons are more efficient.
Consider why we have made such a massive investment to build mankind's single largest machine, the electricity grid. Because engineers recognised that allowing electrons to be produced and distributed by this means was far more efficient than hauling wood, coal or any liquid substance to the point at which power was required.
[从日常经验谈起,建立生物分子和物理电子的紧张态势]Today we live in a connected world; almost everyone has a connected device—cell phones or PDAs. They come in every imaginable shape and size, every colour and set of features. But every last one of them runs not on molecules but electrons; every one of them has a rechargeable battery that is, in most instances, also switchable.
The car is one of the last non-connected devices, but that can be easily changed. Unlike other alternative fuel solutions, the science and technology exist today to make mass-market electric cars a reality.
A study for the Department of Energy finds that "off-peak" electricity production and transmission capacity could fuel 70% of the US light-duty vehicle (LDV) fleet, if they were plug-in hybrid electrics.1 Not only does the capacity exist today on the existing grid, but electric cars can also accelerate the market for renewable energy. Renewable energy has been difficult to capture because it is intermittent[间歇的], but electric cars can [be plugged to堵塞] capture renewable sources of energy at peak times when traditional demand is typically low and that renewable energy is wasted.
What is needed is not a new technology or molecule that we must learn how to produce, distribute and deliver to our vehicles, but a new conduit[导管] to the car—a conduit for electrons rather than molecules.
So why haven't electrons come to[改变,让..接受] transportation so far?
There have been many challenges to the adoption of the electric car, but [the heart of the challenge has been in the cost and range of the battery]. Past generations of batteries were dirty, unreliable, short in range and high in price. Today's batteries continue to be heavy, expensive and range-limited, at least when compared with a similar volume-metric on oil. However, the surprising fact is that today's batteries, when combined with proper infrastructure and business model, can actually deliver a cleaner, more convenient and cost-effective experience than anything else available to drivers today.
To illustrate this, imagine for a moment a plug in every parking spot. The majority of drivers will return to their car to find it has been topped off to the full range of the battery, comfortably 100 miles in a [conventional sedan常规的汽车]. Since the vast majority of trips are within that 100-mile range, a [ubiquitous charge infrastructure无所不在的补给设施] would serve to take the inconvenience of pulling into a service station for a five-minute fill-up out of the driving experience. Add to that a network of battery-switch stations that replace depleted batteries with fully charged ones in less time than it takes to fill up with petrol and the consumer experience is even more compelling. Such a station was successfully demonstrated by Better Place in Yokohama, Japan on May 13th.
With a network of ubiquitous charge-ready parking spots and battery-switch stations, the consumer experience becomes more convenient, with zero stops for energy in the daily routine, and very quick stops at 100-mile intervals on extended trips.
With electricity to power electric cars, we have the opportunity to break our dependence on oil in a meaningful way today and to do it on a global scale. Every element of electrification described is based on customer-ready technology that has minimal barriers to scale.
Meanwhile, alternative liquid fuels [lack any available feedstock capable of scaling] to replace oil today, because of either competition with food crops or the limitations of available land, so that currently proven biofuels have a very [low ceiling of capacity产能的上限很低]. [And even if让步论证] science yielded a form of lab-produced cellulosic ethanol that could reasonably be produced [in volumes] to meaningfully [offset] oil use, there would still be a massive distribution infrastructure required that does not exist today. Finally, because the distribution of electrons is so much more efficient than that of molecules, virtually [any example cited] of success from alternative liquids could be seen as a greater success if those same liquids produced electricity that was then fed to the vehicle by means of the grid.
In a recent study from the University of California Merced, scientists found that biomass converted into electricity produced 81% more transportation miles and 108% more emissions offsets compared with ethanol.
And so, while the future of our transportation energy should be about diversity—particularly about a growing diversity of clean energy sources—this should not confuse the conduit by which this energy is delivered to the vehicle. That conduit should emphatically be for electrons that can be delivered to the car either through direct charge or battery switch. That is the [formula] to give the world the clean and secure energy future that it has so long sought, and it can be executed today.
[反驳观点太强大了!1定义讨论焦点——关键是在能源的输送环节。2电能已经有完善的电网输送设备,而生物能源并没有。3电能的可能性在于不仅可以直充,而且可以用电池;而且电能的效率高。4生物能其实优势并不明显:难以大规模生产,效能低于电能,废物排放高于电能。] |
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